Methods and compositions for treating skin

ABSTRACT

The present disclosure generally relates to methods and compositions for treating skin. In some embodiments, the method uses an exfoliation tool. In some embodiments, the method uses an exfoliation tool together with selected skin care agents or compositions.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. application Ser. No.13/248,367 filed Sep. 29, 2011, which claims benefit to U.S. ProvisionalApplication Ser. No. 61/387,577 filed on Sep. 29, 2010, the entiredisclosures of which are incorporated herein by reference in theirentirety.

FIELD

The present disclosure generally relates to methods and compositions fortreating skin. In some embodiments, the method uses an exfoliation tool.In some embodiments, the method uses an exfoliation tool together withselected skin care agents or compositions.

BACKGROUND

Proper skin care is important for heath and cosmetic reasons. Skin is avital organ and a breakdown in the skin can adversely affect the skin'sfunction as a barrier and make it susceptible to infection. A breakdownin the skin can also be very painful, such as the case of excessive dryskin. Visual irregularities in the skin can adversely affect a person'sconfidence and other people's perceptions.

There remains a need for improved methods of treating skin andmaintaining or improving its health and cosmetic features. It is againstthis background that the present disclosure is made.

SUMMARY

Surprisingly, it has been found that using an exfoliation tool togetherwith selected skin care agents results in improved skin health andappearance.

Accordingly, in some embodiments, the present disclosure relates to amethod of treating skin where a user applies a first skin care agent toskin and treats the skin with an exfoliation tool. In some embodiments,the method also includes additional skin care agents. In someembodiments, the method uses a specific treatment regimen.

In some embodiments, the present disclosure relates to a kit thatincludes an exfoliation tool and selected skin care agents. The kit canalso include specific instructions that explain how to use theexfoliation tool and selected skin care agents.

Finally, in some embodiments, the present disclosure relates to methodsof treating skin using an exfoliation tool and selected skin carecompositions.

These and other embodiments will be apparent to those of skill in theart and others in view of the following detailed description. It shouldbe understood, however, that this summary, and the detailed descriptionillustrate only some examples of various embodiments, and are notintended to be limiting to the claimed invention.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows a view of the exfoliation tool.

FIG. 2 shows a close up of the exfoliation tool head, including theroller and the acupuncture needles.

FIG. 3 shows a person using the exfoliation tool on their face.

DETAILED DESCRIPTION

The present disclosure generally relates to skin treatment using anexfoliation tool and selected skin care agents. While not wanting to bebound by theory, it is believed that the combination of the exfoliationtool and the selected skin care agents increases the uptake of theselected skin care agents by the epidermis (outer layer of skin) than ifthe skin care agent was just placed on top of the epidermis. This isbelieved to be in part because the exfoliation tool increases thesurface area of the epidermis by creating micro pores or holes in theskin, thereby allowing a greater number of skin cells on the epidermisto contact and benefit from the selected skin care agent. One result ofthis is that a user can see improved results in a shorter period oftime.

The Exfoliation Tool

The exfoliation tool of the present disclosure is designed to createmicro pores, channels, or holes in the epidermis or outer layer of theskin. In some embodiments, the exfoliation tool is a roller attached toa handle or wand, such as that shown in FIG. 1. FIG. 1 generally showsan exfoliation tool 10. The exfoliation tool 10 includes a handle orwand 12 and a head 14 attached to the handle 12. The head 14 includes aroller 16. The roller 16 is held in place by a U-shaped collar 18 thatis attached to the handle or wand 12 and engages the roller 16 at eitherend in such a way that allows the roller 16 to rotate. The roller 16includes a plurality of acupuncture needles 20. FIG. 1 shows theacupuncture needles 20 in rows, but it is understood that the needlesmay be arranged in a variety of configurations. The exfoliation tool 10is preferably easily manufactured. In some embodiments, the handle 12,head 14, including the collar 18 and the roller 16 are injection moldedplastic. The acupuncture needles 20 are preferably stainless steel, andmore preferably surgical grade stainless steel.

FIG. 2 shows a close up of the head 14, including the collar 18, roller16, and acupuncture needles 20. The acupuncture needles 20 preferablyform micro holes, pores, or channels in the epidermis of the skin. It isunderstood that other structures may be used instead of acupunctureneedles. When using acupuncture needles, the needles are preferablysolid and made of stainless steel. The needles are preferably from about0.1 mm to about 0.5 mm in length so that when the exfoliation tool isplaced on skin and rolled using moderate pressure, the needles penetrateonly the epidermis, and not the deeper layers of skin. In someembodiments, the needles do not penetrate more than about 100 microns to500 microns into the epidermis.

FIG. 3 shows a person 22 using the exfoliation tool of FIG. 1 on theirface. In some embodiments, the exfoliation tool can be scaled slightlysmaller for use on the face or slightly larger for use on the body orscalp, reflecting the respective differences in surface area of the faceversus the rest of the body or scalp. During use on the face, it may bebeneficial to divide the face into sections such as the forehead, rightside, left side, chin, and neck. A user may then roll the head of theexfoliation tool of FIG. 1 over each section using moderate pressure. Insome embodiments, it may be beneficial for the user to change therolling direction with each pass. A similar method can be used whentreating other body parts or the scalp (i.e., dividing into sections androlling the exfoliation tool over the various sections, changing therolling direction from time to time).

Selected Skin Care Agents

The exfoliation tool may be used in conjunction with at least one skincare agent. The skin care agent is preferably an agent that helpsmaintain, treat, or improve the health or cosmetic appearance of skin.Exemplary skin care agents include the following: abrasives, antiacneagents, antidandruff agents, antifungal agents, antimicrobial agents,antioxidants, toners, moisturizers, skin conditioners, humectants,emollients, skin bleaching or lightening agents, proteins, cleaners,hair conditioners, and the like.

Abrasives may be used to remove unwanted skin such as dead skin cellsand calluses. Exemplary abrasives include but are not limited to thefollowing: alumina, aluminum silicate, apricot seed powder, attapulgite,avocado powder, bamboo powder, barley flour, bentonite, calciumcarbonate, calcium phosphate, calcium pyrophosphate, calcium sulfate,chalk, chitin, coconut shell powder, colloidal oatmeal, comfrey leafpowder, corn cob meal or powder, corn flour, corn meal, corn starch,diamond powder, diatomaceous earth, dicalcium phosphate, dicalcumphosphate dehydrate, egg shell powder, Fuller's earth, hydrated silica,hydroxyapatite, kaolin, kiwi seed, lauryl acrylate polymers, loess,magnesium potassium fluorosilicate, magnesium trisilicate,microcrystalline cellulose, montmorillonite, Moroccan lava clay, oatbran, oat flour, oatmeal, oyster shell powder, peach pit powder, peanutflour, pecan shell powder, polyethylene, pumice, raspberry seed, ricebran, rye flour, sand, silica, sodium bicarbonate, sodium hydroxypropylstarch phosphate, sodium magnesium fluorosilicate, sodiumsilicoaluminate, soybean flour, sweet almond meal, talc, tin oxide,tricalcium phosphate, walnut shell powder, wheat bran, wheat flour,wheat powder, wheat starch, wood powder, zirconium silicate, andderivatives and combinations of these.

Antiacne agents may be used to treat blemishes, pimples, blackheads, andwhiteheads. Exemplary antiacne agents include but are not limited tosalicylic acid, benzoyl peroxide, or sulfur, and their derivatives andcombinations.

Antidandruff agents may be used to treat dandruff, seborrheicdermatitis, or psoriasis. Exemplary antidandruff agents include but arenot limited to the following: coal tar, salicylic acid, seleniumsulfide, sulfur, zinc pyrithione, and their derivatives andcombinations.

Antifungal agents include agents that inhibit the growth andreproduction of fungal cells or decreases the number of fungi present.Exemplary antifungal agents include but are not limited to thefollowing: calcium undecylenate, ketoconazol, povidone-iodine(PVP-iodine), tea tree oil, undecylenic acid, zinc undecylenate, andtheir derivatives and combinations.

Antimicrobial agents include agents that kill microorganisms or preventor inhibit microorganism growth and reproduction or agents that helpprevent infection in minor cuts, scrapes, and burns. Exemplaryantimicrobial agents include but are not limited to the following: lowerchain (C₁-C₄) alcohols, quaternary ammonium compounds such asbenzalkonium chloride and benzethonium chloride, clindamycin,methylbenzethonium chloride, hydrogen peroxide, Oligopeptide-10,phenols, tea tree oil, triclosan, povidone-iodine (PVP-Iodine), andtheir derivatives and combinations.

Antioxidants include agents that are characterized as free radicalscavengers and help reverse skin damage caused by free radicals.Exemplary antioxidants include but are not limited to the following:acetyl cysteine, alpha lipoic acid, arbutin, ascorbic acid (vitamin C),ascorbic acid polypeptide, ascorbyl dipalmitate, ascorbyl methylsilanolpectinate, ascorbyl palmitate, ascorbyl stearate, BHA, BHT, t-butylhydroquinone, caffeic acid, camellia sinensis oil, carotenoids, chitosanascorbate, chitosan glycolate, chitosan salicylate, chlorogenic acids,CoQ10, cortisen, cysteine, cysteine HCl, decyl mercaptomethylimidazole,diamylhydroquinone, di-t-butylhydroquinone, dicetyl thiodipropionate,dicyclopentadiene/t-butylcresol copolymer, digalloyl trioleate, dilaurylthiodipropionate, dimyristyl thiodipropionate, dioleyl tocopherylmethylsilanol, diosmine, disodium ascorbyl sulfate, disodium rutinyldisulfate, distearyl thiodipropionate, ditridecyl thiodipropionate,dodecyl gallate, dunaliella salina extract, erythorbic acid, ethylferulate, ferulic acid, hydroquinone, p-hydroxyanisole, hydroxylamineHCl, hydroxylamine sulfate, hydroxytyrosol, isooctyl thioglycolate,isoquercitrin, kojic acid, madecassicoside, magnesium ascorbate,magnesium ascorbyl phosphate, melatonin, methoxy-PEG-7 rutinylsuccinate, methylene di-t-butylcresol, methylsilanol ascorbate,nordihydroguaiaretic acid, octyl gallate, phenylthioglycloic acid,phloroglucinol, potassium ascorbyl tocopheryl phosphate, potassiumsulfite, propyl gallate, resveratrol, rosmarinic acid, rutin, sirtunis,sodium ascorbate, sodium ascorbyl/cholesteryl phosphate, sodiumbisulfite, sodium erythorbate, sodium metabisulfite, sodium sulfite,sodium thioglycolate, sorbityl furfural, tea tree oil, tetrahexyldecylascorbate, tetrahydrodiferuloylmethane, thiodiglycol, thiodiglycolamide,thiodiglycolic acid, thioglycolic acid, thiolactic acid, thiosalicylicacid, thiotaurine, tocophereth derivatives, tocopherol (vitamin E),tocophersolan, tocopheryl acetate, tocopheryl linoleate, tocopherollinoleate/oleate, tocopheryl nicotinate, tocopheryl succinate,tocoquinone, o-tolyl biguanide, tri(nonylphenyl)phosphate, ubiquinone,vitamin D, zinc dibutyldithiocarbamate, and their derivatives andcombinations.

Toners include agents that create a tightening or tingling sensation onskin. Exemplary toners include but are not limited to the following:alcohol derivatives such as denatured alcohol and SD alcohol, aluminumderivatives such as aluminum acetate, aluminum bromohydrate, aluminumchloride, aluminum chlorohydrex, aluminum citrate, aluminum diacetate,aluminum dichlorohydrate, aluminum dichlorohydrex, aluminum glycinate,aluminum lactate, aluminum phenolsulfonate, aluminumsesquichlorohydrate, aluminum sesquichlorohydrex, and aluminum sulfate,aluminum zirconium derivatives such as aluminum zirconiumoctachlorohydrex, aluminum zirconium pentachlorohydrate, aluminumzirconium pentachlorohydrex, aluminum zirconium tetrachlorohydrate,aluminum zirconium tetrachlorohydrex, aluminum zirconiumtrichlorhydrate, and aluminum zirconium trichlorohydrex, ammonium alum,calcium chloride, calcium lactate, dimethyl MEA, gallic acid, lensesculenta (lentil) seed extract, potassium alum, sodium alum, sodiumaluminum chlorohydroxy lactate, sodium aluminum lactate, tannic acid,tioxolone, tranexamic acid, zinc acetate, zinc chloride, zinc lactate,zinc phenolsulfonate, zinc sulfate, zirconium chlorohydrate, witchhazel, and their derivatives and combinations.

Skin conditioning agents or moisturizers can be classified intodifferent groups such as emollients, humectants, and occlusive agents.Emollients include agents that remain on the upper layers of skin andact as lubricants and improve appearance. Exemplary emollients includebut are not limited to the following: lanolin, glycerides, fruit oils,nut oils, vegetable oils, dimethicones, methicone, cyclomethicone,dormin, fatty acids, myristate derivatives like butyl myristate andmyristyl myristate, oleate derivates, C₁-C₄ glycols, fatty acid glycols,glycol esters, glycerine, glycerols, paraffin, rapeseed oil, long chainalcohols, olive oil, jojoba oil, castor oil, and their derivatives andcombinations. Humectants include agents that increase the water contentof the top layer of skin. Exemplary humectants include but are notlimited to the following: allatoin, agarose, arginine, benzylhyaluronate, chitosan, copper, corn glycerides, gluconolactone, lacticacid, lactobionic acid, lactose, lysine, kombucha, maltitol, maltose,mannitol, propylene glycol, sodium aspartate, fructose, honey, glycerin,hydroxyethyl urea, and their derivatives and combinations. Occlusiveagents slow the evaporation of water from skin. Exemplary occlusiveagents include but are not limited to the following: petrolatum, sheabutter, dimethicones, plant and animal oils such as avacodo, canola, codliver, and corn, mineral oil, olive oil, soybean oil, lanolin,glycerides, beeswax, triglycerides, long chain fatty alcohols, cocobutter, coconut oil, jojoba oil, propylene glycol and their derivativesand combinations.

In addition to skin conditioning agents that provide a moisturizingbenefit, there are other skin conditioning agents that improve theappearance of skin. Exemplary skin conditioning agents include but arenot limited to the following: cholesterol, cystine, hyaluronic acid,keratin, egg yolk, glycine, gluconolactone, lactic acid, lactobionicacid, panthenol, retinol, salicylic acid, vegetable oil, proteins,vitamins, bisabolol, ceramide, coenzyme A, lecithin and theirderivatives and combinations.

Skin bleaching or lightening agents include agents that lighten pigmentin skin. The preferred skin bleaching agent is hydroquinone. Brightenersinclude but are not limited to azelaic acid, bearberry, deoxyarbuten,glycyrrhiza glabra (Licorice) root extract, kojic acid, peat extract,and their derivatives and combinations.

Proteins include animal, plant, fungi, yeast, and bacteria proteins thathave skin health benefits. Exemplary proteins include but are notlimited to the following: collagen, keratin, soy protein, wheat protein,bean palmitate, ascorbic acid polypeptide, the amino acids, casein,cholecalciferol polypeptide, rice protein, silk protein, gluten protein,lysine, acetyl glucosamine, actin, actizyme, albumen, conchiorinprotein, corn protein, egg protein, elastin, fibronectin, gadidaeprotein, hemoglobin, hexapeptide-21, lactalalbumin, lupine protein,maple sycamore protein, milk protein, myristoyl pentapeptide-8,myristoyl tetrapeptide-8, oat protein, oligopeptide 10, palmitoylhexapeptide-14, palmitoyl oligopeptide, palmitoyl tetrapeptide-7, peaprotein, potato protein, reticulin, rice bran protein, serum protein,sweet almond protein, tetrapeptide-16, vegetable protein, yeast protein,palmitoyl oligopeptide, pantothenic acid polypeptides, milk solids,sericin, albumen, amylase, amyloglucosidase, arginine, bromelain,catalase, gelatin, zein, crystallins, cytochrome C, deoxyribonuclease,gliadin, glucose oxidase, glycoproteins, lactoferrin, lactoglubulin,lactoperoxidase, lipase, nisin, oxido reductases, papain, pepsin,subtilisin, sutilains, and their combinations and derivatives.

Cleansers include agents that are used for cleaning the skin and hair bysolubilizing oil and suspending soils. Cleansers may be foaming ornon-foaming. Exemplary cleaners are typically a surfactant and can becharacterized as nonionic, anionic, or zwitterionic.

Nonionic Surfactants.

Nonionic surfactants are generally characterized by the presence of anorganic hydrophobic group and an organic hydrophilic group. The lengthof the hydrophilic moiety can be readily adjusted to yield a waterdispersible or water soluble compound having the desired degree ofbalance between hydrophilic and hydrophobic properties. Exemplarynonionic surfactants include the following:

-   -   Alkylpolysaccharide surfactants that include a hydrophobic group        containing from about 6 to about 30 carbon atoms and a        polysaccharide, e.g., a polyglycoside, hydrophilic group        containing from about 1.3 to about 10 saccharide units. Any        reducing saccharide containing 5 or 6 carbon atoms can be used,        e.g., glucose, galactose and galactosyl moieties can be        substituted for the glucosyl moieties. Exemplary        alkylpolysaccharide surfactants include caproyl ethyl glucoside,        caprylyl/capryl glucoside, coco-glucoside, deceth-7 glucoside,        decyl glucoside,    -   Condensation products of one mole of a saturated or unsaturated,        straight or branched chain alcohol having from about 6 to about        24 carbon atoms with from about 3 to about 50 moles of ethylene        oxide. The alcohol moiety can consist of mixtures of alcohols in        the above delineated carbon range or it can consist of an        alcohol having a specific number of carbon atoms within this        range.    -   Condensation products of one mole of saturated or unsaturated,        straight or branched chain carboxylic acid having from about 8        to about 18 carbon atoms with from about 6 to about 50 moles of        ethylene oxide. The acid can be a mixture of acids in the above        defined carbon atoms range or it can be an acid having a        specific number of carbon atoms within the range.    -   Amine oxides are tertiary amine oxides and semi-polar nonionic        surfactants corresponding to the general formula:

where the arrow=a conventional representation of a semi-polar bond; and,

-   -   R¹, R², and R³ may be aliphatic, aromatic, heterocyclic,        alicyclic, or combinations thereof.

Useful amine oxide surfactants are almondamidopropylamine oxide,babassuamidopropylamine oxide, behenamine oxide, cocamidopropyle amineoxide, cocamine oxide, decylamine oxide, decyltetradecylamine oxide,dihydroxyethyl alkoxyalkylamine oxides, dihydroxyalkyl alkylamineoxides, hydrogenated palm kernel amine oxide, hydrogenated tallowamineoxide, alkoxy alkylamine oxides, isostearamidopropylamine oxide,isostearamidopropyl morpholine oxide, lauramidopropylamine oxide,lauramine oxide, methyl morpholine oxide, milkamidopropyl amine oxide,minkamidopropylamine oxide, myrstamidopropylamine oxide, myrstamineoxide, myristyl/cetyl amine oxide, oleamidopropylamine oxide, oleamineoxide, olivamidopropylamine oxide, palmitamidopropylamine oxide,palmitamine oxide, sesamidopropylamine oxide, soyamidopropylamine oxide,stearamidopropylamine oxide, stearamine oxide, tallowamidopropylamineoxide, tallowamine oxide, undecylenamidopropylamine oxide, wheatgermamidopropylamine oxide.

Anionic Surfactants.

Anionic surfactants includes those with a negative charge on thehydrophobic group or surfactants in which the hydrophobic section of themolecule carries no charge unless the pH is elevated to neutrality orabove (e.g. carboxylic acids). Carboxylate, sulfonate, sulfate andphosphate are the polar (hydrophilic) solubilizing groups found inanionic surfactants. Cations (counter ions) associated with these polargroups include sodium, lithium, potassium, ammonium, substitutedammonium, calcium, barium, and magnesium.

Anionic surfactants can be subdivided into five major chemical classes:(1) acylamino acids (and salts), such as acylgluamates, acyl peptides,sarcosinates (e.g. N-acyl sarcosinates), taurates (e.g. N-acyl tauratesand fatty acid amides of methyl tauride), and the like; (2) carboxylicacids (and salts), such as alkanoic acids (and alkanoates), estercarboxylic acids (e.g. alkyl succinates), ether carboxylic acids, andthe like; (3) phosphoric acid esters and their salts; (4) sulfonic acids(and salts), such as isethionates (e.g. acyl isethionates), alkylarylsulfonates, alkyl sulfonates, sulfosuccinates (e.g. monoesters anddiesters of sulfosuccinate), and the like; and (5) sulfuric acid esters(and salts), such as alkyl ether sulfates, alkyl sulfates, and the like.Exemplary anionic surfactants include the following:

-   -   Linear and branched primary and secondary alkyl sulfates, alkyl        ethoxysulfates, fatty oleyl glycerol sulfates, alkyl phenol        ethylene oxide ether sulfates, the C₅-C₁₇ acyl-N—(C₁-C₄ alkyl)        and —N—(C₁-C₂ hydroxyalkyl) glucamine sulfates, and sulfates of        alkylpolysaccharides such as the sulfates of alkylpolyglucoside        (the nonionic nonsulfated compounds being described herein).        Exemplary alkyl sulfates include ammonium alkyl sulfates,        ammonium cocomonoglyceride sulfates, ammonium dimethicone        copolyol sulfate, ammonium laureth sulfates, ammonium lauryl        sulfates, ammonium myristyl sulfates, ammonium palm kernel        sulfate, diethylamine laureth sulfate, hydroxyethylbutylamine        laureth sulfate, magnesium coco-sulfate, magnesium laureth        sulfate, monoethanolamine and triethanolamine salts of coco,        laureth, and C₁₀-C₁₅ alkyl sulfates, potassium lauryl sulfate,        sodium C₁₂-C₂₀ alkyl sulfates, sodium laureth sulfates, sodium        lauryl sulfate, sodium myristyl sulfate, sodium oleth sulfate,        sodium stearyl sulfate, and sodium tallow sulfate.    -   Ammonium and substituted ammonium (such as mono-, di- and        triethanolamine) and alkali metal (such as sodium, lithium and        potassium) salts of the alkyl mononuclear aromatic sulfonates        such as the alkyl benzene sulfonates containing from 5 to 18        carbon atoms in the alkyl group in a straight or branched chain,        e.g., the salts of alkyl benzene sulfonates, such as ammonium        dodecylbenzenesulfonate.    -   Anionic carboxylate surfactants such as alkyl ethoxy        carboxylates, the alkyl polyethoxy polycarboxylate surfactants        and the soaps (e.g. alkyl carboxyls). Exemplary carboxylate        surfactants include magnesium laureth carboxylate,        monoethanolamine laureth carboxylate, sodium laureth        carboxylates, sodium pareth carboxylates, sodium cocoamide        carboxylates, and sodium trideceth carboxylates.    -   Olefin sulfonates, such as long chain alkene sulfonates, long        chain hydroxyalkane sulfonates or mixtures of alkenesulfonates        and hydroxyalkane-sulfonates, sulfosuccinates, alkyl sulfates,        alkyl poly(ethyleneoxy) ether sulfates and aromatic        poly(ethyleneoxy) sulfates. Exemplary sulfonates include        DEA-methylmyristate sulfonate, magnesium lauryl hydroxypropyl        sulfonate, and the like. Exemplary sulfosuccinates include        ammonium lauryl sulfosuccinates, diammonium lauryl        sulfosuccinates, dioctyl sodium sulfosuccinate, disodum cetearyl        sulfosuccinate, disodium cocamido sulfosuccinates, disodium        coco-glucoside sulfosuccinate, disodium dimethicone copolyol        sulfosuccinate, disodium hydrogenated cottonseed glyceride        sulfosuccinate, disodium isostearyl sulfosuccinate, disodium        laureth sulfosuccinates, and the like.    -   Exemplary sarcosinates include sodium C₁₂-C₁₈ sarcosinates,        sodium cocoyl sarcosinate, and the like. Exemplary taurates        include sodium salts of cocoyl taurate, lauroyl taurate,        myristoyl taurate, palmitoyl taurate, and stearoyl taurate.

Zwitterionic Surfactants.

Zwitterionic surfactants generally contain cationic and anionic groupswhich ionize to a nearly equal degree in the isoelectric region of themolecule and which can develop strong “inner-salt” attraction betweenpositive-negative charge centers.

Zwitterionic surfactants include betaines of the general structure:

Examples of suitable betaines include almondamidopropyl betaine,apricotamidopropyl betain, avocadamidopropyl betaine, babassuamidopropylbetaine, behenamidopropyl betaine, behenyl betaine, canolamidopropylbetaine, cocamidoethyl betaine, cocamidopropyl betaine, coco-betaine,coco/oleamidopropyl betaine, decyl betaine, lauramidopropyl betaine,myristamidopropyl betaine, myristyl betaine, oleamidopropyl betaine,oleyl betaine, palmamidopropyl betaine, olivamidopropyl betaine, stearylbetaine, and the like.

Preferred cleansers include taurates, sulfates, sulfonates,carboxylates, sulfosuccinates, and sarcosinates, zwitterionic betaines,fatty acid and fatty alcohol derivatives, and alkylpolyglucoside andamine oxide surfactants. In some embodiments, the cleansers may becombined with some abrasives such as clays and sulfurs to provide lightexfoliation.

Hair conditioners include agents that enhance the appearance and feel ofhair by improving a property like gloss, texture, or body. Exemplaryhair conditions include but are not limited to the following: lanolin,silicone, dimethicone, proteins such as amino acids, collagen, andkeratin, vitamins, betaine surfactants, amine oxide surfactants,ceramide, fatty acids, eggs, milk, natural plant and animal oils,mineral oil, olive oil, polyquaternium, and their derivatives andcombinations.

The skin care agents may be delivered to the skin individually or in avariety of compositions. For example, the skin care agents may be partof a water-thin liquid, thickened liquid, lotion, cream, gel, emulsionor structured liquid, paste, wax, or solid composition. When formulatedas a composition, the skin care agents may be present with other skincare agents or additional ingredients that impart a skin care benefit orhelp in applying the skin care agent. Exemplary additional ingredientsinclude anticaking agents, antifoaming agents, binders, buffers and pHadjusters, dyes, essential oils, and fragrances, chelating agents,corrosion inhibitors, emulsifiers, emulsion stabilizers, film formers,plasticizers, preservatives, propellants, solvents, foaming agents,hydrotropes, UV light absorbers, thickeners, and the like. When the skincare agents are combined with these additional ingredients, they canform exemplary compositions such as shampoos, conditioners, treatments,cleansers, soaps, toners, lotions, moisturizers, masks, serums, gels,scrubs, exfoliants, and wax blocks.

In some embodiments, the skin care agent or skin care compositions areavailable to users as over-the-counter (“OTC”) products, meaning thatthey are available to users without a doctor's prescription. In someembodiments, the skin care agent or skin care compositions are availableto users through a doctor's prescription. A preferred skin carecomposition includes a combination of proteins, skin conditioners,moisturizers, and antioxidants. Exemplary proteins include sericin,collagen, keratin, amino acids, hexapeptide-21, myristoylpentapeptide-8, myristoyl tetrapeptide-8, oligopeptide 10, palmitoylhexapeptide-14, palmitoyl oligopeptide, palmitoyl tetrapeptide-7,tetrapeptide-16, and derivatives and combinations thereof. Exemplaryskin conditioners include hyaluronic acid, alpha hydroxyl acids (ie:glycolic acid, lactic acid, ascorbic acid), polyhydroxy acids (ie:gluconolactone, lactobionic acid), beta hydroxyl acid, and derivativesand combinations thereof. Exemplary moisturizers include glycerin,dimethicones, triglycerides, natural oils (i.e., olive oil, jojoba oil,soybean oil, coconut oil), silicone, dormin, shea butter, lanolin,glycerides, coco butter, and derivatives and combinations thereof.Exemplary antioxidants include retinol, retinyl palmitate (vitamin A),ascorbic acid (vitamin C), tocopheryl acetate (vitamin E), feverfew,hydroxytyrosol, CoQ10, resveratrol, sirtuins, carotenoids, alpha lipoicacid and derivatives and combinations thereof.

Another preferred skin care composition includes the followingmaterials: water, caprylic/capric triglyceride, Butyrospermum Parkii(shea) butter, cyclopentasiloxane, glycerin, glyceryl stearate, butyleneglycol, stearic acid, Carthamus Tinctorius (Safflower) Seed Oil, stearylalcohol, polysorbate 60, cyclohexasiloxane, sorbitol, dimethicone,dimethicone/vinyl dimethicone crosspolymer, phenoxyethanol, fragrance,caprylyl glycol, retinol, polysorbate 20, ethylhexylglycerin,Glycyrrhiza Glabra (Licorice) Root Extract, BHT, disodium EDTA,dipotassium glycyrrhizate, hexylene glycol, tocopheryl acetate,triethanolamine, carbomer, bisabolol, glyceryl acrylate/acrylic acidcopolymer, sodium hyaluronate, and dye.

Another preferred skin care composition includes the followingmaterials: cyclopentasiloxane, isododecane, dimethicone/bis-isobutylPPG-20 crosspolymer, cyclohexasiloxane, ethoxydiglycol, ascorbic acid,caprylic/capric triglyceride, kojic acid, azelaic acid, ethylhexylhydroxystearate, polysilicone-11, Syringa Vulgaris (Lilac) Leaf cellculture extract, and maltodextrin.

Methods of Using the Exfoliation Tool and the Selected Skin Care Agents

The exfoliation tool and selected skin care agents can be used to treatany skin surface on a human. Exemplary skin surfaces can include thescalp, the face, neck, and décolletage, and the body, such as the back,arms, legs, hands, feet, chest, stomach, and buttocks. The exfoliationtool and skin care agents can be used to treat sensitive skin such asthat found on the face, neck, and décolletage as well as tough skin suchas that found on knees, elbows, hands, and feet. Further, theexfoliation tool and selected skin care agents may be used to treat awide variety of people of all ages, skin colors, and skin types. Forexample, the exfoliation tool and selected skin care agents can be usedto treat people from infants, to children, to teenagers, to adults, andthe elderly. The exfoliation tool and selected skin care agents can beused to treat a variety of skin colors including fair, olive, tan,brown, and black, and all of the variations in between. Finally, theexfoliation tool and selected skin care agents can be used to treat avariety of skin types including dry, normal, oily, sensitive, andacne-prone skin, and combinations of these.

The exfoliation tool and selected skin care agents can be used to treat,maintain, or improve a variety of skin care features or ailments such asskin health and integrity, skin healing, scalp irregularities orailments, and visual or cosmetic irregularities or ailments.

The exfoliation tool and selected skin care agents can be used tomaintain skin health by improving the skin integrity and waterretention. Healthy skin retains water well compared to dry skin. Whenthe exfoliation tool and selected skin care agents are used as directedfor a period of time, the skin should have an improvement intransepidermal water loss (TEWL).

The exfoliation tool and selected skin care agents can be used tomaintain a healthy scalp, or treat or improve scalp irregularities andailments such as dandruff, dry scalp, baldness, hair thinning, andalopecia. The exfoliation tool and selected skin care agents can also beused to improve the health, quality, look or feel of hair by maintaininga healthy scalp, or treating the scalp. For example, the exfoliationtool and selected skin care agents can be used to improve hair texture,hair breakage, hair volume, and hair shine.

Finally, the exfoliation tool and selected skin care agents can be usedto maintain healthy skin, or treat or improve skin irregularities andailments such as scarring, sun damage, fine lines, deep lines orwrinkles, acne, blocked pores, blackheads, dry skin, oily skin,birthmarks, irregular skin tone or color, pore size, stretch marks,uneven texture, age spots, lack of firmness or skin tightness,cellulite, spider veins, fungus, rashes, keritosis pilaris, hair growthin the case of areas where hair growth is undesired, irritation or skinsensitivities, redness, puffiness or bloating, eczema, psoriasis, androsacea.

In some embodiments, the exfoliation tool and the selected skin careagents can be used as part of a skin care regimen where particularagents are used together with the exfoliation tool. For example, whentreating the scalp, it may be beneficial to use the exfoliation toolwith at least one agent that is directed to maintaining, treating, orimproving scalp health and hair loss such as an antidandruff agent, acleanser, a moisturizer, or a hair conditioner. Preferred skin careagents for the scalp include minoxidyl, coal tar, salicylic acid,selenium sulfide, sulfur, zinc pyrithione, and their derivatives andcombinations. In some embodiments, it may be beneficial to use theexfoliation tool with an agent that is part of a shampoo, conditioner,hair mask, scalp treatment, pre-treatment, or other treatment or toniccomposition.

When treating skin on the face, neck, and décolletage, it may bebeneficial to use the exfoliation tool with at least one agent that isdirected to maintaining, treating, or improving skin health such as anabrasive, antiacne agent, antifungal agent, antimicrobial agent,antioxidant, toner, moisturizer, skin conditioner, humectant, emollient,skin bleaching or lightening agent, protein, or cleanser. Preferred skincare agents for the face, neck, and décolletage include retinol,sericin, hexapeptide-21, myristoyl pentapeptide-8, myristoyltetrapeptide-8, oligopeptide 10, palmitoyl hexapeptide-14, palmitoyloligopeptide, palmitoyl tetrapeptide-7, tetrapeptide-16, hyaluronicacid, alpha hydroxyl acids (ie: glycolic acid, lactic acid, ascorbicacid), polyhydroxy acids (ie: gluconolactone, lactobionic acid), betahydroxyl acid, glycerin, silicone, jojoba oil, dormin, shea butter,dimethicones, olive oil, soybean oil, lanolin, glycerides, coco butter,coconut oil, retinyl palmitate (vitamin A), caffeine, ascorbic acid(vitamin C), tocopheryl acetate (vitamin E), feverfew, hydroxytyrosol,CoQ10, resveratrol, sirtuins, carotenoids, alpha lipoic acid,hydroquinone, benzoyl peroxide, sulfur, salicylic acid, actizyme, andderivatives and combinations of these. In some embodiments, it may bebeneficial to use the exfoliation tool with an agent that is part of acleanser, toner, moisturizer, exfoliant, mask, or serum composition.Similar agents and compositions can be used for treating body skin suchas on the arms, legs, hands, feet, back, stomach, and buttocks. Theagents and compositions can be used in varying concentrations andpotentially higher concentrations on body skin versus the sensitive skinsuch as the face, neck, and décolletage. Additional preferred skin careagents include calcium undecylenate, ketoconazol, povidone-iodine(PVP-iodine), tea tree oil, undecylenic acid, zinc undecylenate, lowerchain (C₁-C₄) alcohols, quaternary ammonium compounds such asbenzalkonium chloride and benzethonium chloride, clindamycin,methylbenzethonium chloride, hydrogen peroxide, phenols, triclosan,povidone-iodine (PVP-Iodine), and their derivatives and combinations.

The following table describes some exemplary method embodiments. Thistable is designed to be exemplary only and not limiting:

TABLE A Exemplary Method Embodiments Step 1 Step 2 Step 3 Step 4 Step 5Step 6 Step 7 Step 8 Face, Neck, and Décolletage Treatment CleanserExfoliation Tool Exfoliation Cleanser Tool Cleanser Toner ExfoliationTool Cleanser Exfoliation Toner Tool Cleanser Toner MoisturizerSunscreen Exfoliation Tool Cleanser Toner Exfoliation MoisturizerSunscreen Tool Cleanser Toner Exfoliation Moisturizer Tool CleanserToner Exfoliant Exfoliation Tool Cleanser Toner Moisturizer SunscreenCleanser Toner Exfoliation Moisturizer Tool Body Treatment CleanserExfoliation Tool Exfoliation Cleanser Tool Cleanser ExfoliationMoisturizer Tool Cleanser Exfoliation Treatment Moisturizer ToolCleanser Exfoliation Exfoliant Tool Cleanser Exfoliant ExfoliationMoisturizer Tool Cleanser Exfoliant Exfoliation Moisturizer SunscreenTool Scalp Treatment Shampoo Exfoliation Tool Exfoliation Shampoo ToolShampoo Exfoliation Conditioner Tool Pre- Shampoo ExfoliationConditioner Treatment Tool Scalp Shampoo Exfoliation ConditionerTreatment Tool Hair Mask Exfoliation Shampoo Conditioner Tool ShampooExfoliation Conditioner Treatment Tool Exfoliation Shampoo ConditionerTool Exfoliation Shampoo Treatment Conditioner ToolThe steps in Table A can be performed in any order. Some steps can becombined into a single skin care composition (such as a combination ofmoisturizer and sunscreen). Finally, the steps can take place over time.For example, some steps can be performed in the morning and other stepscan be performed in the evening. Some steps can be performed daily andother steps can be performed less frequently, such as weekly or monthly.

EXAMPLES

The present disclosure may be better understood with reference to thefollowing example. Thus example is intended to be representative ofspecific embodiments of the disclosure, and is not intended as limitingthe scope of the disclosure.

Example 1

Example 1 determined the effect of the exfoliation tool on skin's waterbalance, transepidermal water loss (TEWL), corneometry, and skinelasticity. Also evaluated were the visual effects on skin smoothness,softness, and texture. The example compared a skin care regimen of amask, toner, day cream, serum capsule, and night cream both with andwithout the use of an exfoliation tool in improving skin appearance.

Thirty female subjects over the age of 35 were enrolled in an 8-week,single site, investigator-blinded study. Twenty subjects used a skincare treatment regimen consisting of a cleansing mask, toner, day cream,serum capsules, and night cream. In addition, these subjects also usedan exfoliation tool nightly (every other night for the first 2 weeks,then nightly thereafter). Ten subjects used only the skin care regimenwithout the exfoliation tool. Investigator assessments, subjectassessments, photography, and noninvasive assessments were used toevaluate the effectiveness of the two treatment arms. Subjects wereevaluated at the following time points: baseline, 5 minutes, week 2,week 4, and week 8.

Subjects using the exfoliation tool were instructed to use the cleansingmask, toner, and day cream in the morning and use the cleansing mask,toner, exfoliation tool, serum capsules, and night cream in the eveningin that order. Subjects that did not use the exfoliation tool followedthe same protocol but did not use the exfoliation tool in the evening.

Subject were given the following directions for the products and theexfoliation tool if applicable:

Product 1 Cleansing Mask:

Using wet fingertips, gently and evenly massage a quarter-sized amountonto dry skin. Ensure entire face is covered with a thin coat ofproduct, avoiding contact with eyes. Allow product to dry completely,about 2-3 minutes. Rinse thoroughly; pat dry.

Product 2 Toner:

Shake well before use. Apply evenly to entire face with a gauze pad,avoiding the eye area. Do not rinse off. Allow to dry.

Product 3 Day Cream SPF 30:

Apply a dime-sized amount over entire face every morning. Avoid eyearea.

Product 4 Serum Capsules:

Open capsule and apply serum to the entire face evenly. Use only in theevening.

Product 5 Night Cream:

Apply a dime-sized amount over entire face every evening.

Exfoliation Tool:

For Week 1 and Week 2, use tool every other night after Products 1 and2. For Weeks 3-8, increase to nightly use as tolerated. With moderateand comfortable pressure, roll the tool over entire face and neck 4-10times. For best results, divide the face into sections (forehead, rightside, left side, chin, neck) and treat each section before continuingonto the next. Change the orientation of rolling over each section toensure complete surface coverage. After rolling, apply Product 4 (oneSerum Capsule) over entire face and neck and follow with Product 5(Night Cream).

Subjects were evaluated by collecting observations at baseline, 5minutes, week 2, week 4, and week 8. A dermatologist investigatorperformed all visual assessments. The parameters evaluated consisted of:investigator evaluations, subject evaluations, subject marketingquestionnaire, noninvasive assessments (TEWL, corneometry, elasticity),and photography. The rating scale for evaluation for all subject andinvestigator assessments was: 0=none, 1=minimal, 2=mild, 3=moderate,4=severe.

After the 8-week study, the following results or observations were made:

-   -   The corneometry difference from baseline showed that there was        no statistically significant benefit in skin moisturization with        the exfoliation tool in addition to the skin care products        versus using the skin care products alone. Corneometry is a        measure of the conductivity of the skin utilizing water as the        conductor. More water in the skin indicates superior hydration,        thus a higher corneometry measurement is more favorable.    -   Both groups (with and without the exfoliation tool) showed a        statistically significant improvement in skin moisturization at        weeks 2, 4, and 8. This finding points to the ability of the        skin care regimen to significantly improve skin moisturization.        It is worthwhile noting that the addition of the exfoliation        tool to the skin care products produced highly statistically        significant (p<0.001) improvement in moisturization at weeks 2        and 4, which was not the case with the skin care product alone        group.    -   The corneometry numbers were noticeably higher in the group that        used the exfoliation tool, especially at week 4. This might        directionally point to the value of the exfoliation tool in        improving skin hydration.    -   The investigator noted improvements within both groups over the        8 weeks. At week 2, the investigator noted a statistically        significant improvement in skin texture in all subjects. A        statistically significant improvement was seen in fine lines,        skin texture, and overall appearance with both groups at week 4.        Finally, at week 8, statistically significant improvement was        seen in fine lines, skin texture, and overall appearance. Thus,        the skin care regimen was successful in improving skin        appearance.    -   The investigator direct comparison did not show any        statistically significant differences between the exfoliation        tool plus skin care products and the skin care products group        alone. This could be due to the small sample size or the short        study period. It is possible that new collagen production from        the exfoliation tool might take longer than 12 weeks.    -   No changes in skin elasticity were seen between the exfoliation        tool plus skin care product group and the skin care product        group alone. Skin elasticity is more variable in its        interpretation than the corenometry measurements. Three        elasticity measurements were obtained. The elasticity        measurements were obtained with a suction cup that stretched the        skin into the cup under negative vacuum pressure. Once the skin        was stretched into the top of the cup, such that a light beam at        the top of the cup was broken, the negative vacuum pressure was        discontinued and the skin relaxed. This sequence of events was        repeated three times. With each subsequent iteration of the        suction and relaxation, the skin becomes stretchier and        stretchier and the numbers decreased. Thus, the skin becomes        more elastic with stretching.    -   There was no intragroup difference in skin elasticity between        the exfoliation tool plus skin care product group and the skin        care product group alone. However, it is important to look at        the absolute numbers, since the sample size was small. The skin        elasticity numbers were higher in the exfoliation tool group        than in the skin treatment alone group. This means that it took        more energy to deform the skin of the subjects that used the        exfoliation tool, which can be interpreted as firmer skin        possibly due to a higher water content.    -   No statistically significant differences in skin elasticity were        seen on direct comparison between the exfoliation tool plus skin        care products and skin care products alone group. Again, it is        important to note that the elasticity measurements were higher        at week 8 in the group that used the exfoliation tool plus the        skin care products. This means that the exfoliation tool        improved skin firmness directionally.    -   The subject difference from baseline was used to analyze        intergroup changes. No statistically significant changes were        seen between subject assessments in the exfoliation tool plus        skin care products group or the skin care products alone group        at weeks 2, 4, or 8.    -   The intragroup longitudinal assessment demonstrated that while        both groups of subjects assessed improvement, the improvement        was rated more dramatic in the group that used the exfoliation        tool and skin care products as opposed to the skin care products        alone group. At week 2, there was a statistically significant        improvement in skin softness (p=0.032), skin radiance (p=0.008),        skin evenness (p=0.002), pore appearance (p=0.012), wrinkles        (p=0.006), fine lines (p=0.009), and brown spots (p=0.009). This        is improvement in more attributes than the skin care product        alone group. Statistically significant improvement was seen in        softness, radiance, pores, fine lines, and brown spots with the        exfoliation tool at week 2, which was not the case with the skin        care products alone. However, the skin care products also        elicited excellent ratings by the subjects. There was        statistically significant improvement in evenness (p=0.011) and        wrinkles (p=0.022) at week 2. By week 4, there was statistically        significant improvement in both groups in terms of radiance,        evenness, pores, and wrinkles. At week 4, the exfoliation tool        plus product group outperformed the product group alone with        additional statistically significant improvement in fines lines        (p<0.001), brown spots (p<0.001), and dryness (p=0.047). The        subject assessed differences were the greatest at week 8. The        exfoliation tool group assessed statistically significant        improvements in radiance, evenness, pore appearance, wrinkles,        fine lines, brown spots, and dryness. No statistically        significant increase in irritation was noted pointing toward an        excellent tolerability profile for the exfoliation tool. The        subjects who used the skin care products alone assessed        statistically significant improvement in radiance and evenness.        This means that the use of the exfoliation tool added an        incremental benefit in pore appearance, wrinkles, fine lines,        brown spots and dryness.    -   The direct comparison results were similar to the difference        from baseline results and failed to show much statistically        significant intergroup difference. It appears that with the        study design and small sample size, the longitudinal analysis        was best able to elicit the subtle differences between the two        study groups.    -   No statistically significant differences in TEWL were seen        between the exfoliation tool plus study products group and the        study products alone group.    -   TEWL is a measure of the water leaving the skin. Indeed, TEWL        was increased in the group using the exfoliation tool. This        means that the exfoliation tool did penetrate the skin barrier        and allow more water to escape. A statistically significant        increase in water loss was seen with the exfoliation tool users        as compared to baseline at week 2 (p=0.032) and week 4        (p=0.013). The change was not statistically significant at        week 8. No statistically significant changes in TEWL were seen        in the product use alone group. The TEWL evaluation demonstrates        the ability of the exfoliation tool to produce a physiologic        effect on the skin.    -   No statistically significant differences in TEWL were seen in        the intergroup direct comparison analysis. This means that the        exfoliation tool did not damage the skin in a negative fashion.

The above specification, examples and data provide a completedescription of the use of the disclosed methods and skin care agents.Since many embodiments can be made without departing from the spirit andscope of the disclosure, the invention resides in the claims.

We claim:
 1. A method of skin treatment comprising: (a) applying a firstskin care composition to skin, the skin care composition comprising: i)palmitoyl hexapeptide-14 and an optional peptide selected from the groupconsisting of sericin, collagen, keratin, amino acids, hexapeptide-21,myristoyl pentapeptide-8, myristoyl tetrapeptide-8, oligopeptide 10,palmitoyl oligopeptide, palmitoyl tetrapeptide-7, tetrapeptide-16, andderivatives and combinations thereof; ii) at least one skin conditioningagent selected from the group consisting of emollient, humectant,occlusive agent, hyaluronic acid, alpha hydroxyl acids, glycolic acid,lactic acid, polyhydroxy acids, gluconolactone, lactobionic acid, betahydroxyl acid, and derivatives and combinations thereof; iii)dimethicone and an optional moisturizer selected from the groupconsisting of glycerin, triglycerides, natural oils, olive oil, jojobaoil, soybean oil, coconut oil, silicone, dormin, shea butter, lanolin,coco butter, and derivatives and combinations thereof; and iv) at leastone antioxidant selected from the group consisting of retinol, retinylpalmitate (vitamin A), ascorbic acid (vitamin C), tocopheryl acetate(vitamin E), feverfew, hydroxytyrosol, CoQ 10, resveratrol, sirtuins,carotenoids, alpha lipoic acid, and derivatives and combinationsthereof; and (b) treating the skin with an exfoliation tool.
 2. Themethod of claim 1, wherein the exfoliation tool comprises a handle and ahead, the head comprising a roller, a collar, and a plurality ofacupuncture needles located on the roller.
 3. The method of claim 2,wherein the needles on the exfoliation tool are from about 0.1 mm toabout 0.5 mm.
 4. The method of claim 1, wherein the first skin careagent is applied to skin before treating the skin with the exfoliationtool.
 5. The method of claim 1, wherein the first skin care agent isapplied to skin after treating the skin with the exfoliation tool. 6.The method of claim 1, the method further comprising applying a secondskin care agent to the skin.
 7. The method of claim 6, wherein thesecond skin care agent is applied to skin before treating the skin withthe exfoliation tool.
 8. The method of claim 6, wherein the second skincare agent is applied to skin after treating the skin with theexfoliation tool.
 9. The method of claim 1, wherein the emollient isselected from the group consisting of cyclopentasiloxane, ethylhexylhydroxystearate, methicone, cyclomethicone, dormin, fatty acids, butylmyristate, myristyl myristate, oleate, C₁-C₄ glycols, fatty acidglycols, glycol esters, glycerine, glycerols, paraffin, rapeseed oil,long chain alcohols, and derivatives and combinations thereof.
 10. Themethod of claim 1, wherein the humectant is selected from the groupconsisting of ethyloxydiglycol, allatoin, agarose, arginine, benzylhyaluronate, chitosan, copper, corn glycerides, gluconolactone, lacticacid, lactobionic acid, lactose, lysine, kombucha, maltitol, maltose,mannitol, propylene glycol, sodium aspartate, fructose, honey,hydroxyethyl urea, and derivatives and combinations thereof.
 11. Themethod of claim 1, wherein the composition further comprises at leastone abrasive selected from the group consisting of hydroxyapatite,alumina, aluminum silicate, apricot seed powder, attapulgite, avocadopowder, bamboo powder, barley flour, bentonite, calcium carbonate,calcium phosphate, calcium pyrophosphate, calcium sulfate, chalk,chitin, coconut shell powder, colloidal oatmeal, comfrey leaf powder,corn cob meal or powder, corn flour, corn meal, corn starch, diamondpowder, diatomaceous earth, dicalcium phosphate, dicalcum phosphatedehydrate, egg shell powder, Fuller's earth, hydrated silica, kaolin,kiwi seed, lauryl acrylate polymers, loess, magnesium potassiumfluorosilicate, magnesium trisilicate, microcrystalline cellulose,montmorillonite, Moroccan lava clay, oat bran, oat flour, oatmeal,oyster shell powder, peach pit powder, peanut flour, pecan shell powder,polyethylene, pumice, raspberry seed, rice bran, rye flour, sand,silica, sodium bicarbonate, sodium hydroxypropyl starch phosphate,sodium magnesium fluorosilicate, sodium silicoaluminate, soybean flour,sweet almond meal, talc, tin oxide, tricalcium phosphate, walnut shellpowder, wheat bran, wheat flour, wheat powder, wheat starch, woodpowder, zirconium silicate, and derivatives and combinations.
 12. Themethod of claim 1, wherein the composition further comprisespolysilicone-11.